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Explicit Ions Condensation around Strongly Charged Polyelectrolytes and Spherical Macroions: The Influence of Salt Concentration and Chain Linear Charge Density. Monte Carlo Simulations

Contributeurs/tricesCarnal, Fabrice; Stoll, Sergeorcid
Publié dansThe journal of physical chemistry. A, vol. 116, no. 25, p. 6600-6608
Date de publication2012
Résumé

The condensation of monovalent counterions and trivalent salt particles around strong rigid and flexible polyelectrolyte chains as well as spherical macroions is investigated by Monte Carlo simulations. The results are compared with the condensation theory proposed by Manning. Considering flexible polyelectrolyte chains, the presence of trivalent salt is found to play an important role by promoting chain collapse. The attraction of counterions and salt particles near the polyelectrolyte chains is found to be strongly dependent on the chain linear charge density with a more important condensation at high values. When trivalent salt is added in a solution containing monovalent salt, the trivalent cations progressively replace the monovalent counterions. Ion condensation around flexible chains is also found to be more efficient compared with rigid rods due to monomer rearrangement around counterions and salt cations. In the case of spherical macroions, it is found that a fraction of their bare charge is neutralized by counterions and salt cations. The decrease of the Debye length, and thus the increase of salt concentration, promotes the attraction of counterions and salt particles at the macroion surface. Excluded volume effects are also found to significantly influence the condensation process, which is found to be more important by decreasing the ion size.

Mots-clés
  • Counterion condensation
  • Polyelectrolyte chains
  • Spherical macroions
  • Manning condensation domain
  • Monte Carlo simulations
Citation (format ISO)
CARNAL, Fabrice, STOLL, Serge. Explicit Ions Condensation around Strongly Charged Polyelectrolytes and Spherical Macroions: The Influence of Salt Concentration and Chain Linear Charge Density. Monte Carlo Simulations. In: The journal of physical chemistry. A, 2012, vol. 116, n° 25, p. 6600–6608. doi: 10.1021/jp3010019
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Article (Published version)
accessLevelRestricted
Identifiants
ISSN du journal1089-5639
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Informations techniques

Création13/02/2013 16:45:00
Première validation13/02/2013 16:45:00
Heure de mise à jour14/03/2023 20:03:18
Changement de statut14/03/2023 20:03:18
Dernière indexation16/01/2024 01:13:37
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