UNIGE document Scientific Article
previous document  unige:26052  next document
add to browser collection
Title

Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes

Authors
Published in Organometallics. 2013, vol. 32, no. 2, p. 473-479
Abstract The X-ray structural analyses of homoleptic Rh(II) complexes made of enantiopure (R)-1,1′-binaphthyl and (R)-(5,5′,6,6′,7,7′,8,8′-octahydro)binaphthyl phosphate ligands are for the first time presented. The possibility to introduce halogen atoms at the 3,3′-positions is also reported. The isolated dirhodium complexes were further tested as catalysts (1 mol %) in enantioselective cyclopropanations and Si–H insertion reactions, affording chiral cyclopropanes and silanes in good yield but moderate enantioselectivity (ee max 63%).
Identifiers
Full text
Article (Published version) (2.5 MB) - document accessible for UNIGE members only Limited access to UNIGE
Other version: http://pubs.acs.org/doi/abs/10.1021/om300935u
Structures
Citation
(ISO format)
HRDINA, Radim et al. Synthesis, Structural Analysis, and Catalytic Properties of Tetrakis(binaphthyl or octahydrobinaphthyl phosphate) Dirhodium(II,II) Complexes. In: Organometallics, 2013, vol. 32, n° 2, p. 473-479. https://archive-ouverte.unige.ch/unige:26052

137 hits

5 downloads

Update

Deposited on : 2013-01-30

Export document
Format :
Citation style :