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Title

A Highly Efficient Azide-Based Protecting Group for Amines and Alcohols

Authors
Pothukanuri, Srinivasu
Published in Organic Letters. 2007, vol. 9, no. 11, p. 2223-2225
Abstract The azide-based carbamate or carbonate protecting group (Azoc) shown above can be removed in less than 2 min under neutral conditions using trimethyl or tributyl phosphine as well as polymer-bound triphenyl phosphine. It was shown to be orthogonal to Fmoc and Mtt for peptide synthesis and to afford β-glycoside with a 2-aminoglucosyl donor by virtue of the neighboring group participation.
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Article (Published version) (237 Kb) - document accessible for UNIGE members only Limited access to UNIGE
Other version: http://pubs.acs.org/doi/abs/10.1021/ol0707160
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POTHUKANURI, Srinivasu, WINSSINGER, Nicolas. A Highly Efficient Azide-Based Protecting Group for Amines and Alcohols. In: Organic Letters, 2007, vol. 9, n° 11, p. 2223-2225. https://archive-ouverte.unige.ch/unige:24445

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Deposited on : 2012-12-12

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