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Chromium(III)-trisoxalate, a versatile building block for luminescent materials

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Published in Journal of Luminescence. 2013, vol. 133, p. 15-20
Abstract Chromium(III)-trisoxalate,[Cr(ox)3]3- (ox = C2O42-), incorporated into polymeric networks of composition [NaCr(ox)3][MII(bpy)3] and [NaCr(ox)3][MIII(bpy)3]ClO4 (bpy= 2,2'-bipyridine, MII = Zn, Fe, Ru; MIII = Rh, Cr), results in interesting features ranging from phonon-assisted and resonant energy migration within the R1 line the 2E state to persistent spectral side-hole burning via the latter, and manifestations of specific nearest-neighbour π–π interactions between bipyridine and oxalate.
Keywords Chromium(III)-tris-oxalateEnergy migrationFluorescence line narrowingSpectral diffusionPersistent spectral hole burning
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Research group Groupe Hauser
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MILOS, Mia, HAUSER, Andreas. Chromium(III)-trisoxalate, a versatile building block for luminescent materials. In: Journal of Luminescence, 2013, vol. 133, p. 15-20. https://archive-ouverte.unige.ch/unige:24060

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Deposited on : 2012-11-19

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