C3-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

Renaud, Fabien; Piguet, Claude; Bernardinelli, Gérald Hugues; Hopfgartner, Gerard; Bünzli, Jean-Claude G.

doi:10.1039/a809742i

Scientific article

English

C3-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

ContributorsRenaud, Fabien; Piguet, Claude

; Bernardinelli, Gérald Hugues; Hopfgartner, Gerard

; Bünzli, Jean-Claude G.

Published inChemical communications, p. 457-458

Publication date1999

Abstract

The protonated tripodal podand [L6 + H]+ forms stable and organized monometallic podates [Ln(L6 + H)]4+ where LnIII is facially nine-coordinated by three wrapped unsymmetrical tridentate binding units. An unusual trifurcated hydrogen bond assists the organisation of the covalent tripod.

Affiliation

Citation (ISO format)

RENAUD, Fabien et al. C3-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds. In: Chemical communications, 1999, p. 457–458. doi: 10.1039/a809742i

Article (Accepted version)

Identifiers

PID : unige:2332
DOI : 10.1039/a809742i

Commercial URLhttp://www.rsc.org/delivery/_ArticleLinking/DisplayArticleForFree.cfm?doi=a809742i&JournalCode=CC

ISSN of the journal1359-7345

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C3-Symmetrical lanthanide podates organized by intramolecular trifurcated hydrogen bonds

The protonated tripodal podand [L6 + H]+ forms stable and organized monometallic podates [Ln(L6 + H)]4+ where LnIII is facially nine-coordinated by three wrapped unsymmetrical tridentate binding units. An unusual trifurcated hydrogen bond assists the organisation of the covalent tripod.

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