Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Gaillard, Sylvain; Rix, Diane; Slawin, Alexandra M. Z.; Lacour, Jérôme; Nolan, Steven P.

doi:10.1039/c2dt30440f

Scientific article

English

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

ContributorsGaillard, Sylvain; Rix, Diane; Slawin, Alexandra M. Z.; Lacour, Jérôme

; Nolan, Steven P.

Published inDalton transactions, vol. 41, no. 27, p. 8235-8237

Publication date2012

Abstract

The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

GAILLARD, Sylvain et al. Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour. In: Dalton transactions, 2012, vol. 41, n° 27, p. 8235–8237. doi: 10.1039/c2dt30440f

Article (Published version)

Identifiers

PID : unige:21675
DOI : 10.1039/c2dt30440f

Commercial URLhttp://xlink.rsc.org/?DOI=c2dt30440f

Journal ISSN1477-9226

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Creation21/06/2012 09:24:00

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Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

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