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Scientific article
English

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Published inDalton transactions, vol. 41, no. 27, p. 8235-8237
Publication date2012
Abstract

The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.

Citation (ISO format)
GAILLARD, Sylvain et al. Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour. In: Dalton transactions, 2012, vol. 41, n° 27, p. 8235–8237. doi: 10.1039/c2dt30440f
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ISSN of the journal1477-9226
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Creation06/21/2012 9:24:00 AM
First validation06/21/2012 9:24:00 AM
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