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Title

Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour

Authors
Gaillard, Sylvain
Slawin, Alexandra M. Z.
Nolan, Steven P.
Published in Dalton Transactions. 2012, vol. 41, no. 27, p. 8235-8237
Abstract The synthesis and characterization of a new class of cationic (NHC)gold(I) (NHC = N-Heterocyclic carbene) complex containing the phosphate counterions TRISPHAT and TRISPHAT-N have been achieved. The selection of the appropriate hexacoordinated phosphate architecture permits the isolation of complexes bearing an inner or outer sphere anionic counterion.
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Other version: http://xlink.rsc.org/?DOI=c2dt30440f
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GAILLARD, Sylvain et al. Phosphate binding to the [Au(IPr)] moiety: inner vs. outer sphere coordination behaviour. In: Dalton Transactions, 2012, vol. 41, n° 27, p. 8235-8237. https://archive-ouverte.unige.ch/unige:21675

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Deposited on : 2012-06-27

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