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Scientific article
English

Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

Published inAngewandte Chemie, vol. 51, no. 24, p. 5847-5851
Publication date2012
Abstract

Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion.

Keywords
  • C—H insertion
  • C—O coupling
  • Diazo compounds
  • Enol acetals
  • Tetrahydrofurans
Citation (ISO format)
TORTORETO, Cecilia et al. Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes. In: Angewandte Chemie, 2012, vol. 51, n° 24, p. 5847–5851. doi: 10.1002/anie.201201541
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ISSN of the journal1433-7851
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Technical informations

Creation06/05/2012 3:31:00 PM
First validation06/05/2012 3:31:00 PM
Update time03/14/2023 5:37:01 PM
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