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Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

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Published in Angewandte Chemie: International Edition. 2012, vol. 51, no. 24, p. 5847-5851
Abstract Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion.
Keywords C—H insertionC—O couplingDiazo compoundsEnol acetalsTetrahydrofurans
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TORTORETO, Cecilia et al. Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes. In: Angewandte Chemie: International Edition, 2012, vol. 51, n° 24, p. 5847-5851. https://archive-ouverte.unige.ch/unige:21495

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Deposited on : 2012-06-06

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