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Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes |
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Published in | Angewandte Chemie: International Edition. 2012, vol. 51, no. 24, p. 5847-5851 | |
Abstract | Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion. | |
Keywords | C—H insertion — C—O coupling — Diazo compounds — Enol acetals — Tetrahydrofurans | |
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Citation (ISO format) | TORTORETO, Cecilia et al. Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes. In: Angewandte Chemie: International Edition, 2012, vol. 51, n° 24, p. 5847-5851. doi: 10.1002/anie.201201541 https://archive-ouverte.unige.ch/unige:21495 |