Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

Tortoreto, Cecilia; Achard, Thierry; Zeghida, Walid; Austeri, Martina; Guenee, Laure; Lacour, Jérôme

doi:10.1002/anie.201201541

Scientific article

English

Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

ContributorsTortoreto, Cecilia; Achard, Thierry; Zeghida, Walid; Austeri, Martina; Guenee, Laure; Lacour, Jérôme

Published inAngewandte Chemie, vol. 51, no. 24, p. 5847-5851

Publication date2012

Abstract

Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion.

Keywords

C—H insertion
C—O coupling
Diazo compounds
Enol acetals
Tetrahydrofurans

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

TORTORETO, Cecilia et al. Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes. In: Angewandte Chemie, 2012, vol. 51, n° 24, p. 5847–5851. doi: 10.1002/anie.201201541

Article (Published version)

Identifiers

PID : unige:21495
DOI : 10.1002/anie.201201541

ISSN of the journal1433-7851

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Creation06/05/2012 3:31:00 PM

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Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion.

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