Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes

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Title		Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes
Authors		Tortoreto, Cecilia Achard, Thierry Zeghida, Walid Austeri, Martina Guenee, Laure Lacour, Jérôme
Published in		Angewandte Chemie: International Edition. 2012, vol. 51, no. 24, p. 5847-5851
Abstract		Intermolecular C—O instead of —CC bond formation is achieved with [CpRu(CH3CN)3][PF6] and diimine ligands as catalysts of the decomposition of α-diazo-β-ketoesters in THF leading to original products of 1,3 CH insertion.
Keywords		C—H insertion — C—O coupling — Diazo compounds — Enol acetals — Tetrahydrofurans
Identifiers		DOI: 10.1002/anie.201201541
Full text		Article (Published version) (582 Kb) - Limited access to UNIGE
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		TORTORETO, Cecilia et al. Enol Acetal Synthesis through Carbenoid C—H Insertion into Tetrahydrofuran Catalyzed by CpRu Complexes. In: Angewandte Chemie: International Edition, 2012, vol. 51, n° 24, p. 5847-5851. doi: 10.1002/anie.201201541 https://archive-ouverte.unige.ch/unige:21495

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Deposited on : 2012-06-06

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