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Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes

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Published in Angewandte Chemie: International Edition. 2012, vol. 51, no. 16, p. 3826-3831
Abstract Three-in-one: A short synthetic route readily gives access to a new class of chiral (P,N) ligands characterized by three distinct elements of chirality. These ligands are highly enantioselective in the challenging Pd-catalyzed intramolecular asymmetric α-arylation of α-branched aldehydes (see picture).
Keywords α-arylationAsymmetric catalysisLigand designOxidative additionPalladium
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Other version: http://doi.wiley.com/10.1002/anie.201108061
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NAREDDY, Pradeep et al. Atropoisomeric (P,N) Ligands for the Highly Enantioselective Pd-Catalyzed Intramolecular Asymmetric α-Arylation of α-Branched Aldehydes. In: Angewandte Chemie: International Edition, 2012, vol. 51, n° 16, p. 3826-3831. https://archive-ouverte.unige.ch/unige:19419

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Deposited on : 2012-04-17

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