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Self-organizing surface-initiated polymerization of perylenediimides on indium tin oxides

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Published in Chemical Science. 2012, vol. 3, no. 5, p. 1492-1496
Abstract In this study, we demonstrate, for the first time, that SOSIP, self-organizing surface-initiated polymerization, a method introduced for facile access to complex surface architectures, is compatible with perylenediimides (PDIs), i.e., established chromophores with very important properties. Highly ordered face-to-face π-stacks are shown to coincide with a more than 100-fold increase of the activity of PDI photosystems, and with significant fill factors. This breakthrough with electron-transporting PDI stacks promises access to powerful combinations with hole-transporting channels.
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Other version: http://xlink.rsc.org/?DOI=c2sc01047j
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CHARBONNAZ, Pierre, SAKAI, Naomi, MATILE, Stefan. Self-organizing surface-initiated polymerization of perylenediimides on indium tin oxides. In: Chemical Science, 2012, vol. 3, n° 5, p. 1492-1496. https://archive-ouverte.unige.ch/unige:19403

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Deposited on : 2012-04-16

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