Scientific article
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English

A Sweet Introduction to the Mathematical Analysis of Time-Resolved Spectra and Complex Kinetic Mechanisms: The Chameleon Reaction Revisited

Published inJournal of chemical education, vol. 99, no. 6, p. 2327-2337
Publication date2022-05-23
First online date2022-05-23
Abstract

We present a detailed yet easy-to-follow discussion of the mathematical treatment of time-resolved spectroscopic data in a model-based approach. This is accompanied and complemented by an example of a colorful and pedagogically rich chemical reaction: the permanganate oxidation of sugars in basic aqueous media (often known as the chameleon reaction). Our sweet approach allows both students and lecturers to tackle the problem of a model-based analysis of time-resolved data in a simple manner and one step at the time, while also exercising programming and data analysis skills─fundamental for present and future chemists of all levels.

Keywords
  • Carbohydrates
  • Chemical reactions
  • Kinetic modeling
  • Kinetics
  • Physical Chemistry
  • Computer-Based Learning
  • Problem Solving/Decision Making
  • Mathematics/Symbolic Mathematics
  • Mechanisms of Reactions
  • Oxidation/Reduction
  • Spectroscopy
Affiliation entities Not a UNIGE publication
Citation (ISO format)
FERNÁNDEZ-TERÁN, Ricardo José et al. A Sweet Introduction to the Mathematical Analysis of Time-Resolved Spectra and Complex Kinetic Mechanisms: The Chameleon Reaction Revisited. In: Journal of chemical education, 2022, vol. 99, n° 6, p. 2327–2337. doi: 10.1021/acs.jchemed.2c00104
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Article (Published version)
Identifiers
Additional URL for this publicationhttps://pubs.acs.org/doi/10.1021/acs.jchemed.2c00104
Journal ISSN0021-9584
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158downloads

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