Interaction between photoexcited aqua-uranyl (VI) and perchlorate

Marcantonatos, Minas; Deschaux, Michel; Celardin, Fredi; Levental, Mario

doi:10.1016/0009-2614(79)87072-4

Scientific article

English

Interaction between photoexcited aqua-uranyl (VI) and perchlorate

ContributorsMarcantonatos, Minas; Deschaux, Michel; Celardin, Fredi; Levental, Mario

Published inChemical physics letters, vol. 65, no. 2, p. 316-321

Publication date1979-08-15

Abstract

In sufficient concentrations, perchlorate is found to produce a decrease in the decay and an exaltation of the luminescence of aqueous acidic solutions of uranyl. This is shown to be due to the excited-state interaction between excited uranyl and perchlorate, giving a complex in which the oxidative activity of the UO²⁺₂ moiety towards water is diminished.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Citation (ISO format)

MARCANTONATOS, Minas et al. Interaction between photoexcited aqua-uranyl (VI) and perchlorate. In: Chemical physics letters, 1979, vol. 65, n° 2, p. 316–321. doi: 10.1016/0009-2614(79)87072-4

Article (Published version)

Identifiers

PID : unige:184494
DOI : 10.1016/0009-2614(79)87072-4

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/0009261479870724

Journal ISSN0009-2614

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Interaction between photoexcited aqua-uranyl (VI) and perchlorate

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