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Efficient soft-chemical synthesis of large van-der-Waals crystals of the room-temperature ferromagnet 1T-CrTe2

First online date2025
Abstract

We herein report on a fast and convenient soft-chemical synthesis approach towards large 1T-CrTe2 van-der-Waals crystals. This compound is formed X-ray diffraction pure, with a complete conversion within just over 2 h from flux-grown LiCrTe2 crystals using diluted acids. Due to the availability of high-quality single crystals, we have confirmed the crystal structure for the first time by single-crystal X-ray diffraction experiments. For the acid deintercalated 1T-CrTe2 crystals, we find long-range ferromagnetic order with a Curie temperature of T C = 318 K. We further revealed the magnetic structure of 1T-CrTe2 using low-temperature neutron powder diffraction experiments and determined the magnetic Hamiltonian using density functional theory. X-ray diffraction experiments of post-annealed crystals suggest a thermal stability of 1T-CrTe2 up to at least 100 °C. Our findings expand the synthesis methods for 1T-CrTe2 crystals, which hold promise for integrated room-temperature spintronics applications.

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Citation (ISO format)
ROESELER, Kai et al. Efficient soft-chemical synthesis of large van-der-Waals crystals of the room-temperature ferromagnet 1T-CrTe2. In: Journal of materials chemistry. A, 2025. doi: 10.1039/D4TA05649C
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Additional URL for this publicationhttps://xlink.rsc.org/?DOI=D4TA05649C
Journal ISSN2050-7496
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Creation20/01/2025 13:37:24
First validation22/01/2025 12:47:08
Update time22/01/2025 12:47:08
Status update22/01/2025 12:47:08
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