Article (Published version) (364 Kb) - 
Limited access to UNIGE
Highlights
Scientific Article
unige:18209 
 |
Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic Alkylation |
|
| Authors | ||
| Published in | Angewandte Chemie: International Edition. 2012, vol. 51, no. 4, p. 1055-1058 | |
| Abstract | A select few: Several prochiral enyne chlorides were employed as substrates in the title reaction using Grignard reagents as the alkylation reagents (see scheme; CuTC=copper(I) thiophenecarboxylate). Excellent 1,3 substitution regioselectivities and good to excellent enantioselectivities were obtained. The substrate scope is additionally extended to diene chlorides. | |
| Keywords | Alkylation — Asymmetric catalysis — Copper — Enynes — Grignard reagents | |
| Identifiers | ||
| Full text | ||
| Structures | ||
| Citation (ISO format) | LI, Hailing, ALEXAKIS, Alexandre. Enyne Chlorides: Substrates for Copper-Catalyzed Asymmetric Allylic Alkylation. In: Angewandte Chemie: International Edition, 2012, vol. 51, n° 4, p. 1055-1058. doi: 10.1002/anie.201107129 https://archive-ouverte.unige.ch/unige:18209 |
480 hits 
7 downloads 
Contact an author
Update