Molecular Fe(ii)–Ln(iii) dyads for luminescence reading of spin-state equilibria at the molecular level

Lathion, Timothee; Deorukhkar, Neel; Glaus, Charlotte; Nozary, Homayoun; Piguet, Claude

doi:10.1039/d4dt01868k

Scientific article

Review

English

Molecular Fe(ii)–Ln(iii) dyads for luminescence reading of spin-state equilibria at the molecular level

ContributorsLathion, Timothee

; Deorukhkar, Neel; Glaus, Charlotte; Nozary, Homayoun; Piguet, Claude

Published inDalton transactions, vol. 53, no. 44, p. 17756-17765

Publication date2024

First online date2024

Abstract

Efficient and easy lanthanide( iii )-based luminescence reading of iron( ii ) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Research groups

Groupe Piguet

Funding

Swiss National Science Foundation - Earth abundant and kinetically inert chromium(III) and iron(II) chromophores for modulating the luminescence of 4f-block cations in (supra)molecular edifices. [207313]

Citation (ISO format)

LATHION, Timothee et al. Molecular Fe(ii)–Ln(iii) dyads for luminescence reading of spin-state equilibria at the molecular level. In: Dalton transactions, 2024, vol. 53, n° 44, p. 17756–17765. doi: 10.1039/d4dt01868k

Article (Published version)

CC BY-4.0

Identifiers

PID : unige:181462
DOI : 10.1039/d4dt01868k
PMID : 39311462
PMCID : PMC11418352

Additional URL for this publicationhttps://xlink.rsc.org/?DOI=D4DT01868K

Journal ISSN1477-9226

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Molecular Fe(ii)–Ln(iii) dyads for luminescence reading of spin-state equilibria at the molecular level

Efficient and easy lanthanide( iii )-based luminescence reading of iron( ii ) spin-state equilibria presents an attractive challenge, owing to the delicate combination of the primogenic effect and the Fermi golden rule.

Technical informations