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Uncatalyzed and catalyzed oscillatory reactions in the system: 1,2-dihydroxy-3,5-benzenedisulfonic acid disodium salt (tiron) / BrO-3/H2SO4. Kinetic study of decrease in tiron concentration by HPLC

Published inChimia, vol. 38, no. 1, p. 8-11
Publication date1984
Abstract

Oscillatory behaviour in the redox potential of the tiron/BrO-3/H2SO4 system is reported for the uncatalyzed, the cerium (IV) as well as the ferroin catalyzed systems. The effect of temperature, the rate of decrease in [tiron] were investigated for the catalyzed and uncatalyzed systems. Pentabromoacetone, a reaction product, was isolated from the reaction medium.

Citation (ISO format)
HABASHI-KRAYENBUHL, Dominique Marie Sophie, DOGAN, Selim, JANJIC, Desimir. Uncatalyzed and catalyzed oscillatory reactions in the system: 1,2-dihydroxy-3,5-benzenedisulfonic acid disodium salt (tiron) / BrO-3/H2SO4. Kinetic study of decrease in tiron concentration by HPLC. In: Chimia, 1984, vol. 38, n° 1, p. 8–11. doi: 10.2533/chimia.1984.8
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Journal ISSN0009-4293
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