Scientific article
English

Electron capture in single crystals of triphenylmethylarsonium iodide. Electron spin resonance detection of Ph3AsI

Published inJournal of the Chemical Society. Faraday Transactions I, vol. 82, no. 2, p. 521-525
Publication date1986
Abstract

A study of the angular variation of the e.s.r. signals obtained with an X-irradiated single crystal of Ph3As+CH3I(g-tensor, 75As and 127I hyperfine tensors) showed that the radiogenic adduct Ph3As⋯ĊH3 gave rise to the arsoranyl radical Ph3ȦsI. The mechanism which leads from Ph3As+CH3 to Ph3ȦsI, via the successive formation of Ph3ȦsCH3 and Ph3As⋯ĊH3, is discussed.

Citation (ISO format)
GEOFFROY, Michel, LLINARES, Antoine, MISHRA, Shuddhodan P. Electron capture in single crystals of triphenylmethylarsonium iodide. Electron spin resonance detection of Ph3AsI. In: Journal of the Chemical Society. Faraday Transactions I, 1986, vol. 82, n° 2, p. 521–525. doi: 10.1039/F19868200521
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Additional URL for this publicationhttps://xlink.rsc.org/?DOI=f19868200521
Journal ISSN0300-9599
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