Nuclear quadrupole resonance and stereochemistry. Part 6, Transmission of substituent effects through a double bond

Ardalan, Ziba; Delay, François; Geoffroy, Michel; Lucken, Edwin-Anthony; Masson, S.

doi:10.1039/p29760001867

Scientific article

English

Nuclear quadrupole resonance and stereochemistry. Part 6, Transmission of substituent effects through a double bond

ContributorsArdalan, Ziba; Delay, François; Geoffroy, Michel; Lucken, Edwin-Anthony; Masson, S.

Published inJournal of the Chemical Society. Perkin transactions II, no. 15, p. 1867-1868

Publication date1976

Abstract

The ³⁵CI quadrupole resonance frequencies of a variety of pairs of cis-trans-isomers of chloroethylenes and of bridged bicyclic chloroethylenes are reported. The results show that cis-substituents produce small but significantly greater frequency shifts than do trans-substituents.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Citation (ISO format)

ARDALAN, Ziba et al. Nuclear quadrupole resonance and stereochemistry. Part 6, Transmission of substituent effects through a double bond. In: Journal of the Chemical Society. Perkin transactions II, 1976, n° 15, p. 1867–1868. doi: 10.1039/p29760001867

Article (Published version)

Identifiers

PID : unige:178963
DOI : 10.1039/p29760001867

Additional URL for this publicationhttps://xlink.rsc.org/?DOI=p29760001867

Journal ISSN0300-9580

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Nuclear quadrupole resonance and stereochemistry. Part 6, Transmission of substituent effects through a double bond

The 35CI quadrupole resonance frequencies of a variety of pairs of cis-trans-isomers of chloroethylenes and of bridged bicyclic chloroethylenes are reported. The results show that cis-substituents produce small but significantly greater frequency shifts than do trans-substituents.

Technical informations

The ³⁵CI quadrupole resonance frequencies of a variety of pairs of cis-trans-isomers of chloroethylenes and of bridged bicyclic chloroethylenes are reported. The results show that cis-substituents produce small but significantly greater frequency shifts than do trans-substituents.