A free-radical intermediate in the thermal rearrangement of oxime thionocarbamates

Hudson, R.F.; Lawson, A.J.; Lucken, Edwin-Anthony

doi:10.1039/C29710000807

Scientific article

English

A free-radical intermediate in the thermal rearrangement of oxime thionocarbamates

ContributorsHudson, R.F.; Lawson, A.J.; Lucken, Edwin-Anthony

Published inJournal of the Chemical Society. Chemical communications, no. 15, p. 807-808

Publication date1971

Abstract

A transient free-radical species has been detected by e.s.r. measurements in the thermal rearrangement of oxime thionocarbamates to thioxime carbamates, and evidence is presented which is consistent with this radical being an intermediate in the rearrangement.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Citation (ISO format)

HUDSON, R.F., LAWSON, A.J., LUCKEN, Edwin-Anthony. A free-radical intermediate in the thermal rearrangement of oxime thionocarbamates. In: Journal of the Chemical Society. Chemical communications, 1971, n° 15, p. 807–808. doi: 10.1039/C29710000807

Article (Published version)

Identifiers

PID : unige:178764
DOI : 10.1039/C29710000807

Commercial URLhttps://xlink.rsc.org/?DOI=c29710000807

ISSN of the journal0022-4936

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A free-radical intermediate in the thermal rearrangement of oxime thionocarbamates

A transient free-radical species has been detected by e.s.r. measurements in the thermal rearrangement of oxime thionocarbamates to thioxime carbamates, and evidence is presented which is consistent with this radical being an intermediate in the rearrangement.

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