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Title

Conformationally Stabilized Catalysts by Fluorine Insertion: Tool for Enantioselectivity Improvement
Authors
Quintard, Adrien
Langlois, Jean-Baptiste
Emery, Daniel
Mareda, Jiri
Guenee, Laure
Alexakis, Alexandre
Published in Chemistry - A European Journal. 2011, vol. 17, no. 48, p. 13433-13437
Abstract F rigid cats: The power of conformationally stabilized catalysts is demonstrated. By taking appropriate advantage of fluorine insertion (see scheme), purely conformational catalyst design led to a notable improvement in enantioselectivities from around 70 % to 91–98.5 % ee. The other advantage of this approach is the better understanding of the origin of the stereoselectivity in the given catalytic system.
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Article (Published version) (605 Kb) - document accessible for UNIGE members only Limited access to UNIGE
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Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée
Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation
(ISO format) 		QUINTARD, Adrien et al. Conformationally Stabilized Catalysts by Fluorine Insertion: Tool for Enantioselectivity Improvement. In: Chemistry - A European Journal, 2011, vol. 17, n° 48, p. 13433-13437. doi: 10.1002/chem.201102757 https://archive-ouverte.unige.ch/unige:17736

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Deposited on : 2011-12-06

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