Axially-chiral boramidine for detailed (chir)optical studies

SALEH, Nidal et al. Axially-chiral boramidine for detailed (chir)optical studies. In: Chemical science, 2024, vol. 15, n° 17, p. 6530–6535. doi: 10.1039/D4SC00870G

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Identifiers

PID : unige:177327
DOI : 10.1039/D4SC00870G
PMID : 38699281
PMCID : PMC11062121

Additional URL for this publicationhttps://xlink.rsc.org/?DOI=D4SC00870G

Journal ISSN2041-6520

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Creation27/05/2024 08:31:45

First validation27/05/2024 11:47:06

Update time04/10/2024 13:37:29

Status update04/10/2024 13:37:29

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Axially-chiral boramidine for detailed (chir)optical studies

An axially-chiral boramidine displays UV-absorption, deep-blue fluorescence ( Φ up to 94%), and |10 −3 | g abs and g lum . Deactivation pathways of the emissive state to triplet excited states, involving increased spin–orbit coupling, are identified.

Technical informations

An axially-chiral boramidine displays UV-absorption, deep-blue fluorescence ( Φ up to 94%), and |10 ⁻³ | g _abs and g _lum . Deactivation pathways of the emissive state to triplet excited states, involving increased spin–orbit coupling, are identified.