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Scientific article
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Study of the behaviour of solid-state membrane electrodes. Part II: Role of adsorption of fluoride ions on fluoride ion-selective electrode and determination of solubility of the membrane

Published inAnalytica chimica acta, vol. 68, no. 2, p. 253-266
Publication date1974-02
Abstract

The phenomena limiting the sensitivity of the fluoride-selective electrode are described. Although the interference of electrolyte ions or fluoride impurities can play a part in this lower detection limit, it seems that the adsorption of fluoride ions at the membrane-solution interface and the solubility of the electrode crystal are the two principal parameters. The solubility of the electrode crystal under different conditions was estimated.

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Citation (ISO format)
BUFFLE, Jacques, PARTHASARATHY, Nalini, HAERDI, Werner. Study of the behaviour of solid-state membrane electrodes. Part II: Role of adsorption of fluoride ions on fluoride ion-selective electrode and determination of solubility of the membrane. In: Analytica chimica acta, 1974, vol. 68, n° 2, p. 253–266. doi: 10.1016/S0003-2670(01)82580-0
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