Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work

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Title		Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work
Authors		Vargas Jentzsch, Rodrigo Andreas Emery, Daniel Mareda, Jiri Metrangolo, Pierangelo Resnati, Giuseppe Matile, Stefan
Published in		Angewandte Chemie. 2011, vol. 50, no. 49, p. 11675-11678
Abstract		Single-atom exchange series are introduced to extract the individual contributions of halogen bonds and anion–π interactions to the transport of anions across lipid bilayer membranes (see picture). Known cation binding sites are used for counterion activation of the neutral calix[4]arene transporters. The experimental evidence for anion transport with halogen bonds is unprecedented.
Keywords		Anions — Anion transport — Anion–π interactions — Halogen bonds
Identifiers		DOI: 10.1002/anie.201104966
Full text		Article (Published version) (723 Kb) - Limited access to UNIGE Article (Accepted version) (1.4 MB) - Free access
Structures		Faculté des sciences / Section de chimie et biochimie / Département de chimie organique
Citation (ISO format)		VARGAS JENTZSCH, Rodrigo Andreas et al. Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work. In: Angewandte Chemie, 2011, vol. 50, n° 49, p. 11675-11678. doi: 10.1002/anie.201104966 https://archive-ouverte.unige.ch/unige:17654