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Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work |
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Published in | Angewandte Chemie. 2011, vol. 50, no. 49, p. 11675-11678 | |
Abstract | Single-atom exchange series are introduced to extract the individual contributions of halogen bonds and anion–π interactions to the transport of anions across lipid bilayer membranes (see picture). Known cation binding sites are used for counterion activation of the neutral calix[4]arene transporters. The experimental evidence for anion transport with halogen bonds is unprecedented. | |
Keywords | Anions — Anion transport — Anion–π interactions — Halogen bonds | |
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Citation (ISO format) | VARGAS JENTZSCH, Rodrigo Andreas et al. Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work. In: Angewandte Chemie, 2011, vol. 50, n° 49, p. 11675-11678. doi: 10.1002/anie.201104966 https://archive-ouverte.unige.ch/unige:17654 |