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Title

Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work

Authors
Metrangolo, Pierangelo
Resnati, Giuseppe
Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 49, p. 11675-11678
Abstract Single-atom exchange series are introduced to extract the individual contributions of halogen bonds and anion–π interactions to the transport of anions across lipid bilayer membranes (see picture). Known cation binding sites are used for counterion activation of the neutral calix[4]arene transporters. The experimental evidence for anion transport with halogen bonds is unprecedented.
Keywords AnionsAnion transportAnion–π interactionsHalogen bonds
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Other version: http://doi.wiley.com/10.1002/anie.201104966
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VARGAS JENTZSCH, Rodrigo Andreas et al. Ditopic Ion Transport Systems: Anion-π Interactions and Halogen Bonds at Work. In: Angewandte Chemie: International Edition, 2011, vol. 50, n° 49, p. 11675-11678. https://archive-ouverte.unige.ch/unige:17654

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Deposited on : 2011-12-01

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