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Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF4 and [Pt(AMP)(dmso)Cl]ClO4

Published inTransition metal chemistry, vol. 17, no. 6, p. 579-582
Publication date1992-12
Abstract

Treatment of [M(AMP)Cl2] (M = PtII, PdII; AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO4, BF4, PF6) in dmso yields [M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the PdII and PtII complexes indicate that dmso is S-bondedtrans to the pyridyl ring in both complexes.

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Citation (ISO format)
AL-ALLAF, Tallal et al. Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF<sub>4</sub> and [Pt(AMP)(dmso)Cl]ClO<sub>4</sub>. In: Transition metal chemistry, 1992, vol. 17, n° 6, p. 579–582. doi: 10.1007/BF02910763
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ISSN of the journal0340-4285
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