Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF<sub>4</sub> and [Pt(AMP)(dmso)Cl]ClO<sub>4</sub>

Al-Allaf, Tallal; Castan, Paule; Turpin, Reine; Wimmer, Smita; Bernardinelli, Gérald Hugues

doi:10.1007/BF02910763

Scientific article

English

Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF₄ and [Pt(AMP)(dmso)Cl]ClO₄

ContributorsAl-Allaf, Tallal; Castan, Paule; Turpin, Reine; Wimmer, Smita; Bernardinelli, Gérald Hugues

Published inTransition metal chemistry, vol. 17, no. 6, p. 579-582

Publication date1992-12

Abstract

Treatment of [M(AMP)Cl₂] (M = Pt^II, Pd^II; AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO₄, BF₄, PF₆) in dmso yields [M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the Pd^II and Pt^II complexes indicate that dmso is S-bondedtrans to the pyridyl ring in both complexes.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie minérale, analytique et appliquée

Citation (ISO format)

AL-ALLAF, Tallal et al. Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF₄ and [Pt(AMP)(dmso)Cl]ClO₄. In: Transition metal chemistry, 1992, vol. 17, n° 6, p. 579–582. doi: 10.1007/BF02910763

Article (Published version)

Identifiers

PID : unige:176045
DOI : 10.1007/BF02910763

Journal ISSN0340-4285

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Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF4 and [Pt(AMP)(dmso)Cl]ClO4

Treatment of [M(AMP)Cl2] (M = PtII, PdII; AMP = 2-aminomethylpyridine) with 1 mole of AgX (X = ClO4, BF4, PF6) in dmso yields [M(AMP)(dmso)Cl]X. Single crystal X-ray structure determinations of the PdII and PtII complexes indicate that dmso is S-bondedtrans to the pyridyl ring in both complexes.

Technical informations

Solvolysis of palladium(II) and platinum(II) complexes of asymmetric ligands: synthesis and structural characterization of [Pd(AMP)(dmso)Cl]BF₄ and [Pt(AMP)(dmso)Cl]ClO₄