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English

Programming heterometallic 4f–4f′ helicates under thermodynamic control: the circle is complete

Published inDalton transactions, vol. 53, no. 13, p. 6050-6062
Publication date2024
First online date2024
Abstract

The use of pair interactions and specific site affinities provides 63% of the heterotrimetallic HHH -[(L4 3 Zn)LaEu] 8+ helicate in solution where statistics predicts only 25% of this isomer under thermodynamic control for a stoichiometric ratio of 1 : 1 : 1.

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Citation (ISO format)
GLAUS, Charlotte et al. Programming heterometallic 4f–4f′ helicates under thermodynamic control: the circle is complete. In: Dalton transactions, 2024, vol. 53, n° 13, p. 6050–6062. doi: 10.1039/d4dt00610k
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ISSN of the journal1477-9226
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