en
Scientific article
English

Controlling Symmetry-Breaking Charge Separation in Pyrene Bichromophores

Published inThe journal of physical chemistry letters, vol. 15, no. 10, p. 2834-2840
Publication date2024-03-05
First online date2024-03-05
Abstract

So far, symmetry-breaking charge separation (SB-CS) has been observed with a limited number of chromophores and is usually inhibited by the formation of an excimer. We show here that thanks to fine-tuning of the interchromophore coupling via structural control, SB-CS can be operative with pyrene, despite its high propensity to form an excimer. This is realized with a bichromophoric system consisting of two pyrenes attached to a crown ether macrocycle, which can bind cations of different sizes. By combining stationary and time-resolved spectroscopy together with molecular dynamics simulations, we demonstrate that the excited-state dynamics can be totally changed depending on the binding cation. Whereas strong coupling leads to rapid excimer formation, too weak coupling results in noninteracting chromophores. However, intermediate coupling, achieved upon binding of Mg2+, allows for SB-CS to be operative.

eng
Citation (ISO format)
WEGA, Johannes et al. Controlling Symmetry-Breaking Charge Separation in Pyrene Bichromophores. In: The journal of physical chemistry letters, 2024, vol. 15, n° 10, p. 2834–2840. doi: 10.1021/acs.jpclett.4c00337
Main files (2)
Article (Published version)
accessLevelRestricted
Article (Accepted version)
accessLevelRestrictedaccessLevelPublic 03/06/2025
Identifiers
ISSN of the journal1948-7185
29views
0downloads

Technical informations

Creation03/15/2024 6:54:12 AM
First validation03/18/2024 9:23:49 AM
Update time03/18/2024 9:23:49 AM
Status update03/18/2024 9:23:49 AM
Last indexation05/06/2024 6:11:06 PM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack