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Scientific article
English

Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species

Published inAngewandte Chemie, vol. 50, no. 47, p. 11162-11166
Publication date2011
Abstract

A highly porous form of Mg(BH4)2 (see picture; Mg green, BH4 blue, unit cells shown in red) reversibly absorbs H2, N2, and CH2Cl2. At high pressures, this material transforms into an interpenetrated framework that has 79 % higher density than the other polymorphs. Mg(BH4)2 can act as a coordination polymer that has many similarities to metal–organic frameworks.

Keywords
  • Framework materials
  • Host-guest systems
  • Hydrides
  • Hydrogen storage
  • Polymorphism
Research group
Citation (ISO format)
FILINCHUK, Yaroslav et al. Porous and Dense Magnesium Borohydride Frameworks: Synthesis, Stability, and Reversible Absorption of Guest Species. In: Angewandte Chemie, 2011, vol. 50, n° 47, p. 11162–11166. doi: 10.1002/anie.201100675
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Article (Published version)
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ISSN of the journal1433-7851
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Creation11/16/2011 11:44:00 AM
First validation11/16/2011 11:44:00 AM
Update time03/14/2023 5:04:27 PM
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