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Controlling crystal cleavage in Focused Ion Beam shaped specimens for surface spectroscopy

Published inReview of scientific instruments, vol. 95, 033905
Publication date2024-03-08
Abstract

Our understanding of quantum materials is commonly based on precise determinations of their electronic spectrum by spectroscopic means, most notably angle-resolved photoemission spectroscopy (ARPES) and scanning tunneling microscopy (STM). Both require atomically clean and flat crystal surfaces which traditionally are prepared by in-situ mechanical cleaving in ultrahigh vacuum chambers. We present a new approach that addresses three main issues of the current state-of-the-art methods: 1) Cleaving is a highly stochastic and thus inefficient process; 2) Fracture processes are governed by the bonds in a bulk crystal, and many materials and surfaces simply do not cleave; 3) The location of the cleave is random, preventing data collection at specified regions of interest. Our new workflow is based on Focused Ion Beam (FIB) machining of micro-stress lenses in which shape (rather than crystalline) anisotropy dictates the plane of cleavage, which can be placed at a specific target layer. As proof-of-principle we show ARPES results from micro-cleaves of Sr2RuO4 along the ac plane and from two surface orientations of SrTiO3, a notoriously difficult to cleave cubic perovskite.

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Citation (ISO format)
HUNTER, Andrew Scott et al. Controlling crystal cleavage in Focused Ion Beam shaped specimens for surface spectroscopy. In: Review of scientific instruments, 2024, vol. 95, p. 033905. doi: 10.1063/5.0186480
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ISSN of the journal0034-6748
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