<i>Pfeiffer</i> effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

Pal, David; Lacour, Jérôme

doi:10.1039/D3DT04098D

Scientific article

Open access

English

Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

ContributorsPal, David

; Lacour, Jérôme

Published inDalton transactions

Publication date2024

First online date2024

Abstract

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na ⁺ and K ⁺ at 20 °C.

Affiliation

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Research group

Groupe Lacour

Citation (ISO format)

PAL, David, LACOUR, Jérôme. <i>Pfeiffer</i> effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles. In: Dalton transactions, 2024. doi: 10.1039/D3DT04098D

Article (Published version)

CC BY

Identifiers

PID : unige:174383
DOI : 10.1039/D3DT04098D

Commercial URLhttp://xlink.rsc.org/?DOI=D3DT04098D

ISSN of the journal1477-9226

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Creation23.01.2024 14:33:16

First validation24.01.2024 13:52:07

Update time24.01.2024 13:52:07

Status update24.01.2024 13:52:07

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Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na + and K + at 20 °C.

Technical informations

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na ⁺ and K ⁺ at 20 °C.