<i>Pfeiffer</i> effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

Pal, David; Lacour, Jérôme

doi:10.1039/D3DT04098D

Scientific article

English

Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

ContributorsPal, David

; Lacour, Jérôme

Published inDalton transactions

Publication date2024

First online date2024

Abstract

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na ⁺ and K ⁺ at 20 °C.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Research groups

Groupe Lacour

Citation (ISO format)

PAL, David, LACOUR, Jérôme. Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles. In: Dalton transactions, 2024. doi: 10.1039/D3DT04098D

Article (Published version)

CC BY

Identifiers

PID : unige:174383
DOI : 10.1039/D3DT04098D

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=D3DT04098D

Journal ISSN1477-9226

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Creation23/01/2024 14:33:16

First validation24/01/2024 13:52:07

Update time24/01/2024 13:52:07

Status update24/01/2024 13:52:07

Last indexation10/06/2025 21:53:59

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Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na + and K + at 20 °C.

Technical informations

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na ⁺ and K ⁺ at 20 °C.