UNIGE document Scientific Article
previous document  unige:17329  next document
add to browser collection
Title

New Catalytic Asymmetric Strategies to Access Chiral Aldehydes

Author
Published in Chimia. 2011, vol. 65, no. 10, p. 802-805
Abstract The present article describes the recent catalytic asymmetric methods developed in our group to access enantioenriched chiral aldehydes. We are generally aiming at developing complementary strategies based on either homogeneous organometallic catalysts or amino-catalysts and sometimes on a combination of both. Recent successes comprise a perfectly redox-economical iridium-catalyzed asymmetric isomerization of primary allylic alcohols under very mild conditions and the development of a transition metal-catalyzed anti-Markovnikov asymmetric hydroboration of 1,1-disubstituted olefins. The developments of these two processes along with preliminary mechanistic investigations are presented herein.
Keywords ASYMMETRIC CATALYSISCHIRAL ALDEHYDESHYDROBORATIONIRIDIUMISOMERIZATION
Identifiers
Full text
Article (Published version) (253 Kb) - public document Free access
Structures
Citation
(ISO format)
MAZET, Clement. New Catalytic Asymmetric Strategies to Access Chiral Aldehydes. In: Chimia, 2011, vol. 65, n° 10, p. 802-805. doi: 10.2533/chimia.2011.802 https://archive-ouverte.unige.ch/unige:17329

448 hits

371 downloads

Update

Deposited on : 2011-11-04

Export document
Format :
Citation style :