Scientific article
English

Retention of iodine in yttria stabilized zirconia

Publication date1999-01
Abstract

The diffusion behavior of iodine in yttria stabilized zirconia (YSZ) was investigated as a function of the temperature. Iodine implantation was performed in this cubic solid solution by irradiating material samples with 1 MeV iodine ions. The distribution of iodine was evaluated by using TRIM computer calculation and measured by Rutherford backscattering spectrometry (RBS) using 5 MeV 4He particle. The iodine profile was quantified after successive temperature steps. At each step the maximum temperature was held for 2 h. It was found, that the iodine profile remained unchanged up to 1373 K. At 1573 K iodine diffused significantly. The iodine profile was measurable up to 1773 K. Even at this high temperature a significant iodine retention is observed. The diffusion coefficient of iodine (3.5 ± 1.4 × 10−15 cm2 s−1) is of the same order as the temperature extrapolated data of iodine in monoclinic/tetragonal zirconia.

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Citation (ISO format)
POUCHON, Manuel Alexandre, DÖBELI, M., DEGUELDRE, Claude. Retention of iodine in yttria stabilized zirconia. In: Nuclear instruments & methods in physics research. Section B, Beam interactions with materials and atoms, 1999, vol. 148, n° 1-4, p. 783–786. doi: 10.1016/S0168-583X(98)00885-4
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Journal ISSN0168-583X
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