Scientific article
English

Reaction of Bicyclo[3.2.1]octenols with Thionyl Chloride. Preliminary paper

Published inHelvetica chimica acta, vol. 54, no. 5, p. 1482-1483
Publication date1971
Abstract

The allylic 1-methyl-3-bromobicyclo[3.2.1]octenyl exo-2 and exo-4 alcohols were treated with thionyl chloride in ether or pentane solution at 0°. In each case, a 50/50 mixture of exo allylic chlorides was obtained. No evidence for a predominant SNi'′reaction was detected; reported cases of such SNi'′ processes using these conditions should therefore be treated with reserve.

Citation (ISO format)
JEFFORD, Charles, GUNSHER, J.A. Reaction of Bicyclo[3.2.1]octenols with Thionyl Chloride. Preliminary paper. In: Helvetica chimica acta, 1971, vol. 54, n° 5, p. 1482–1483. doi: 10.1002/hlca.19710540531
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Journal ISSN0018-019X
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