Steric effects on reaction rates. II: Rate and equilibrium constants for oxidation of bicyclic alcohols

Muller, Paul; Blanc, Jacky

doi:10.1016/0040-4039(81)80131-1

Scientific article

Letter

English

Steric effects on reaction rates. II: Rate and equilibrium constants for oxidation of bicyclic alcohols

ContributorsMuller, Paul; Blanc, Jacky

Published inTetrahedron letters, vol. 22, no. 8, p. 715-718

Publication date1981

Abstract

Equilibrium constants for oxidation of a series of bicyclic alcohols with cyclohexanone have been determined under Meerwein-Ponndorf conditions. The data provide the thermodynamic background for interpretation of the mechanism of alcohol oxidation and ketone reductions. Free energies of the equilibrium (ΔG_ox) are compared with values calculated by molecular mechanics.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, BLANC, Jacky. Steric effects on reaction rates. II: Rate and equilibrium constants for oxidation of bicyclic alcohols. In: Tetrahedron letters, 1981, vol. 22, n° 8, p. 715–718. doi: 10.1016/0040-4039(81)80131-1

Article (Published version)

Identifiers

PID : unige:169157
DOI : 10.1016/0040-4039(81)80131-1

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/0040403981801311

Journal ISSN0040-4039

88views

0downloads

Creation26/05/2023 08:40:37

First validation26/05/2023 10:54:07

Update time26/05/2023 10:54:07

Status update26/05/2023 10:54:07

Last indexation01/11/2024 05:11:48

Archive ouverte UNIGE

Steric effects on reaction rates. II: Rate and equilibrium constants for oxidation of bicyclic alcohols

Technical informations