Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene

Muller, Paul; Godoy Aniorte, José Andrés

doi:10.1002/hlca.19810640807

Scientific article

English

Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene

ContributorsMuller, Paul; Godoy Aniorte, José Andrés

Published inHelvetica chimica acta, vol. 64, no. 8, p. 2531-2533

Publication date1981-12-16

First online date2004-10-25

Abstract

Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, GODOY ANIORTE, José Andrés. Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene. In: Helvetica chimica acta, 1981, vol. 64, n° 8, p. 2531–2533. doi: 10.1002/hlca.19810640807

Article (Published version)

Identifiers

PID : unige:169154
DOI : 10.1002/hlca.19810640807

Additional URL for this publicationhttps://onlinelibrary.wiley.com/doi/10.1002/hlca.19810640807

Journal ISSN0018-019X

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Ru-Catalyzed Oxidation of Acetylenes to α-Diketones with Iodosylbenzene

Disubstituted acetylenes are oxidized with PhIO in presence of Ru‐catalysts to afford α‐diketones in 65–85% yield. Under the same conditions terminal acetylenes are cleaved to carboxylic acids.

Technical informations