A Stereoselective Approach to the Spiro [4, 5]decane System <i>via</i> Intramolecular Photocycloaddition and Reductive Fragmentation. Preliminary communication

Von Oppolzer, Wolfgang; Gorrichon, Liliane Maryse; Bird, T. Geoffrey C.

doi:10.1002/hlca.19810640120

Scientific article

English

A Stereoselective Approach to the Spiro [4, 5]decane System via Intramolecular Photocycloaddition and Reductive Fragmentation. Preliminary communication

ContributorsVon Oppolzer, Wolfgang; Gorrichon, Liliane Maryse; Bird, T. Geoffrey C.

Published inHelvetica chimica acta, vol. 64, no. 1, p. 186-187

Publication date1981-02-04

Abstract

The photoaddition 6→7, followed by a reductive cleavage of the →‐chlorocyclobutylketone 7, gave the stereochemically pure spiro [4,5]decane 8.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

VON OPPOLZER, Wolfgang, GORRICHON, Liliane Maryse, BIRD, T. Geoffrey C. A Stereoselective Approach to the Spiro [4, 5]decane System via Intramolecular Photocycloaddition and Reductive Fragmentation. Preliminary communication. In: Helvetica chimica acta, 1981, vol. 64, n° 1, p. 186–187. doi: 10.1002/hlca.19810640120

Article (Published version)

Identifiers

PID : unige:169151
DOI : 10.1002/hlca.19810640120

Additional URL for this publicationhttps://onlinelibrary.wiley.com/doi/10.1002/hlca.19810640120

Journal ISSN0018-019X

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A Stereoselective Approach to the Spiro [4, 5]decane System via Intramolecular Photocycloaddition and Reductive Fragmentation. Preliminary communication

The photoaddition 6→7, followed by a reductive cleavage of the →‐chlorocyclobutylketone 7, gave the stereochemically pure spiro [4,5]decane 8.

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