Evidence for a charge-transfer mechanism in the photo-oxygenation of an enamine

Martin, Ned Harold; Jefford, Charles

doi:10.1016/S0040-4039(01)82034-7

Scientific article

Letter

English

Evidence for a charge-transfer mechanism in the photo-oxygenation of an enamine

ContributorsMartin, Ned Harold; Jefford, Charles

Published inTetrahedron letters, vol. 22, no. 40, p. 3949-3952

Publication date1981

Abstract

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MARTIN, Ned Harold, JEFFORD, Charles. Evidence for a charge-transfer mechanism in the photo-oxygenation of an enamine. In: Tetrahedron letters, 1981, vol. 22, n° 40, p. 3949–3952. doi: 10.1016/S0040-4039(01)82034-7

Article (Published version)

Identifiers

PID : unige:168876
DOI : 10.1016/S0040-4039(01)82034-7

Commercial URLhttps://linkinghub.elsevier.com/retrieve/pii/S0040403901820347

Journal ISSN0040-4039

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Evidence for a charge-transfer mechanism in the photo-oxygenation of an enamine

Evidence for a charge-transfer mechanism in the photo-oxygenation of the enamine form of 1-benzyl-3,4-dihydroisoquinolines is presented. Substituent effects, normalized to constant enamine concentration, fit best a mechanism involving the formation of a rate-determining charge-transfer complex.

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