Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene

Muller, Paul; Godoy Aniorte, José Andrés

doi:10.1016/S0040-4039(00)88651-7

Scientific article

Letter

English

Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene

ContributorsMuller, Paul; Godoy Aniorte, José Andrés

Published inTetrahedron letters, vol. 23, no. 36, p. 3661-3664

Publication date1982

Abstract

Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44–85% yield. These conversions can also be effected with RuO₄.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, GODOY ANIORTE, José Andrés. Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene. In: Tetrahedron letters, 1982, vol. 23, n° 36, p. 3661–3664. doi: 10.1016/S0040-4039(00)88651-7

Article (Published version)

Identifiers

PID : unige:168552
DOI : 10.1016/S0040-4039(00)88651-7

Commercial URLhttps://linkinghub.elsevier.com/retrieve/pii/S0040403900886517

Journal ISSN0040-4039

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Ru-catalyzed oxidation of substituted acetylenes to α-keto esters and α-keto amides with iodosylbenzene

Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44–85% yield. These conversions can also be effected with RuO4.

Technical informations

Oxidation of alkynyl ethers and -amines with iodosylbenzene in presence of Ru-catalysts affords α-keto esters and α-keto amides in 44–85% yield. These conversions can also be effected with RuO₄.