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Scientific article
Letter
English

High asymmetric induction in Diels-Alder additions of cyclopentadiene to acrylates derived from isoborneol

Published inTetrahedron letters, vol. 23, no. 46, p. 4781-4784
Publication date1982
Abstract

Starting from (R)-(+)- and from (S)-(−)-camphor the chiral alcohols 1, 2 and 3 have been prepared; their acrylates II underwent TiCl2(OR)2-promoted Diels-Alder additions to cyclopentadiene giving efficiently in a predictable manner either the (2R)- or the (2S)-adducts III with up to virtually quantitative asymmetric induction.

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Citation (ISO format)
VON OPPOLZER, Wolfgang et al. High asymmetric induction in Diels-Alder additions of cyclopentadiene to acrylates derived from isoborneol. In: Tetrahedron letters, 1982, vol. 23, n° 46, p. 4781–4784. doi: 10.1016/S0040-4039(00)85712-3
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ISSN of the journal0040-4039
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