en
Scientific article
English

Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols

Published inHelvetica chimica acta, vol. 66, no. 6, p. 1790-1795
Publication date1983-09-21
First online date2004-10-25
Abstract

Oxidation of sulfides with PhIO/RuCl2 (PPh3)3 leads to sulfones. Electronwithdrawing substituents in the aromatic ring of PhIO reduce the reactivity and improves selectivity of the system. Thus, with m-iodosylbenzoic acid sulfides are converted to sulfoxide. Under the same conditions aliphatic primary alcohols are transformed to aldehydes with m-iodosylbenzoic acid, while PhIO affords carboxylic acids.

eng
Citation (ISO format)
MULLER, Paul, GODOY ANIORTE, José Andrés. Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols. In: Helvetica chimica acta, 1983, vol. 66, n° 6, p. 1790–1795. doi: 10.1002/hlca.19830660618
Main files (1)
Article (Published version)
accessLevelRestricted
Identifiers
ISSN of the journal0018-019X
22views
0downloads

Technical informations

Creation04/14/2023 8:36:13 AM
First validation04/14/2023 10:18:03 AM
Update time04/14/2023 10:18:03 AM
Status update04/14/2023 10:18:03 AM
Last indexation02/01/2024 9:55:05 AM
All rights reserved by Archive ouverte UNIGE and the University of GenevaunigeBlack