Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols

Muller, Paul; Godoy Aniorte, José Andrés

doi:10.1002/hlca.19830660618

Scientific article

English

Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols

ContributorsMuller, Paul; Godoy Aniorte, José Andrés

Published inHelvetica chimica acta, vol. 66, no. 6, p. 1790-1795

Publication date1983-09-21

First online date2004-10-25

Abstract

Oxidation of sulfides with PhIO/RuCl₂ (PPh₃)₃ leads to sulfones. Electronwithdrawing substituents in the aromatic ring of PhIO reduce the reactivity and improves selectivity of the system. Thus, with m-iodosylbenzoic acid sulfides are converted to sulfoxide. Under the same conditions aliphatic primary alcohols are transformed to aldehydes with m-iodosylbenzoic acid, while PhIO affords carboxylic acids.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, GODOY ANIORTE, José Andrés. Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols. In: Helvetica chimica acta, 1983, vol. 66, n° 6, p. 1790–1795. doi: 10.1002/hlca.19830660618

Article (Published version)

Identifiers

PID : unige:168194
DOI : 10.1002/hlca.19830660618

Additional URL for this publicationhttps://onlinelibrary.wiley.com/doi/10.1002/hlca.19830660618

Journal ISSN0018-019X

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Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols

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