en
Scientific article
Letter
English

Asymmetric Michael addition of a chiral ester-dienolate: enantioselective synthesis of (−)-khusimone

Published inTetrahedron letters, vol. 24, no. 45, p. 4975-4978
Publication date1983
Abstract

A double π-face-selective aprotic Michael addition of the lithium dienolate derived from the chiral senecioate 2b to cyclopentenone coupled with recovery of the auxiliary 14 serves for the enantioselective synthesis of (−)-khusimone (12) (Schemes 1 and 4).

eng
Citation (ISO format)
VON OPPOLZER, Wolfgang et al. Asymmetric Michael addition of a chiral ester-dienolate: enantioselective synthesis of (−)-khusimone. In: Tetrahedron letters, 1983, vol. 24, n° 45, p. 4975–4978. doi: 10.1016/S0040-4039(01)99825-9
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ISSN of the journal0040-4039
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