Rh-catalyzed oxidation of anthracenes to anthraquinones using <i>t</i>-butylhydroperoxide

Muller, Paul; Bobillier, Christiane

doi:10.1016/S0040-4039(00)94122-4

Scientific article

Letter

English

Rh-catalyzed oxidation of anthracenes to anthraquinones using t-butylhydroperoxide

ContributorsMuller, Paul; Bobillier, Christiane

Published inTetrahedron letters, vol. 24, no. 49, p. 5499-5500

Publication date1983

Abstract

Rh-catalyzed oxidation of 2-substituted anthracene with t-butylhydroperoxide affords anthraquinones in yields up to 90%, while V-catalyzed oxidation and stoichiometric oxidation with CrO₃ are less efficient.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, BOBILLIER, Christiane. Rh-catalyzed oxidation of anthracenes to anthraquinones using t-butylhydroperoxide. In: Tetrahedron letters, 1983, vol. 24, n° 49, p. 5499–5500. doi: 10.1016/S0040-4039(00)94122-4

Article (Published version)

Identifiers

PID : unige:168183
DOI : 10.1016/S0040-4039(00)94122-4

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/S0040403900941224

Journal ISSN0040-4039

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Rh-catalyzed oxidation of anthracenes to anthraquinones using t-butylhydroperoxide

Rh-catalyzed oxidation of 2-substituted anthracene with t-butylhydroperoxide affords anthraquinones in yields up to 90%, while V-catalyzed oxidation and stoichiometric oxidation with CrO3 are less efficient.

Technical informations

Rh-catalyzed oxidation of 2-substituted anthracene with t-butylhydroperoxide affords anthraquinones in yields up to 90%, while V-catalyzed oxidation and stoichiometric oxidation with CrO₃ are less efficient.