The reaction of trimethylsilyl α-trimethylsilylperoxy esters with ketones and aldehydes. A simple, efficient synthesis of 1,2,4-trioxan-5-ones

Jefford, Charles; Rossier, Jean-Claude; Richardson, Geoffrey David

doi:10.1039/C39830001064

Scientific article

English

The reaction of trimethylsilyl α-trimethylsilylperoxy esters with ketones and aldehydes. A simple, efficient synthesis of 1,2,4-trioxan-5-ones

ContributorsJefford, Charles; Rossier, Jean-Claude; Richardson, Geoffrey David

Published inJournal of the Chemical Society. Chemical communications, no. 19, p. 1064-1065

Publication date1983

Abstract

The title compounds readily react in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulphonate to give the corresponding 3,6-substituted 1,2,4-trioxan-5-ones in good yields.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles, ROSSIER, Jean-Claude, RICHARDSON, Geoffrey David. The reaction of trimethylsilyl α-trimethylsilylperoxy esters with ketones and aldehydes. A simple, efficient synthesis of 1,2,4-trioxan-5-ones. In: Journal of the Chemical Society. Chemical communications, 1983, n° 19, p. 1064–1065. doi: 10.1039/C39830001064

Article (Published version)

Identifiers

PID : unige:168059
DOI : 10.1039/C39830001064

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=C39830001064

Journal ISSN0022-4936

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The reaction of trimethylsilyl α-trimethylsilylperoxy esters with ketones and aldehydes. A simple, efficient synthesis of 1,2,4-trioxan-5-ones

The title compounds readily react in the presence of a catalytic amount of trimethylsilyl trifluoromethanesulphonate to give the corresponding 3,6-substituted 1,2,4-trioxan-5-ones in good yields.

Technical informations