Preparation, structure and asymmetric Diels-Alder reactions of 10-arylsulfonylisobornyl acrylates

Von Oppolzer, Wolfgang; Kelly, Martha Jean; Bernardinelli, Gérald Hugues

doi:10.1016/S0040-4039(01)81712-3

Scientific article

Letter

English

Preparation, structure and asymmetric Diels-Alder reactions of 10-arylsulfonylisobornyl acrylates

ContributorsVon Oppolzer, Wolfgang; Kelly, Martha Jean; Bernardinelli, Gérald Hugues

Published inTetrahedron letters, vol. 25, no. 51, p. 5889-5892

Publication date1984

Abstract

The crystalline chiral auxiliaries 4 and 5 were readily prepared from camphorsulfonic acid. Their acrylates underwent the diels-alder reactions 6 → 7 with modest asymmetric induction consistent with an X-ray study of 6a.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

VON OPPOLZER, Wolfgang, KELLY, Martha Jean, BERNARDINELLI, Gérald Hugues. Preparation, structure and asymmetric Diels-Alder reactions of 10-arylsulfonylisobornyl acrylates. In: Tetrahedron letters, 1984, vol. 25, n° 51, p. 5889–5892. doi: 10.1016/S0040-4039(01)81712-3