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Scientific article
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English

Synthesis of [9.10-b]-Phenanthrofuran via Ring Expansion of a Dichlorocyclopropane

Published inChimia, vol. 38, no. 3, p. 79-80
Publication date1984-03
Abstract

Base-induced elimination of the dichlorocarbene adduct 8 of 9-mcthoxyphenamhrene (7) give rise to the formation of the phenanthrofuran 9. A mechanism involving a cyclopropene-vinyl-carbene rearrangement (10-11) followed by intramolecular insertion into the C-H bond of 11 is proposed for the transformation.

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Citation (ISO format)
MULLER, Paul, PFYFFER, Jean. Synthesis of [9.10-b]-Phenanthrofuran<i> via</i> Ring Expansion of a Dichlorocyclopropane. In: Chimia, 1984, vol. 38, n° 3, p. 79–80.
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  • PID : unige:167929
ISSN of the journal0009-4293
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