Reactions of cyclic peroxides with aldehydes and ketones catalysed by trimethylsilyl trifluoromethanesulphonate. An efficient synthesis of 1,2,4-trioxanes

Jefford, Charles; Boukouvalas, John; Kohmoto, Shigeo

doi:10.1039/C39840000523

Scientific article

English

Reactions of cyclic peroxides with aldehydes and ketones catalysed by trimethylsilyl trifluoromethanesulphonate. An efficient synthesis of 1,2,4-trioxanes

ContributorsJefford, Charles; Boukouvalas, John; Kohmoto, Shigeo

Published inJournal of the Chemical Society. Chemical communications, no. 8, p. 523-524

Publication date1984

Abstract

Trimethylsilyl trifluoromethanesulphonate is found to be an efficient catalyst for the reaction of 1,4-endoperoxides and 1,2-dioxetanes with aldehydes and ketones to give 1,2,4-trioxanes in high yields.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles, BOUKOUVALAS, John, KOHMOTO, Shigeo. Reactions of cyclic peroxides with aldehydes and ketones catalysed by trimethylsilyl trifluoromethanesulphonate. An efficient synthesis of 1,2,4-trioxanes. In: Journal of the Chemical Society. Chemical communications, 1984, n° 8, p. 523–524. doi: 10.1039/C39840000523

Article (Published version)

Identifiers

PID : unige:167915
DOI : 10.1039/C39840000523

Additional URL for this publicationhttp://xlink.rsc.org/?DOI=c39840000523

Journal ISSN0022-4936

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Reactions of cyclic peroxides with aldehydes and ketones catalysed by trimethylsilyl trifluoromethanesulphonate. An efficient synthesis of 1,2,4-trioxanes

Trimethylsilyl trifluoromethanesulphonate is found to be an efficient catalyst for the reaction of 1,4-endoperoxides and 1,2-dioxetanes with aldehydes and ketones to give 1,2,4-trioxanes in high yields.

Technical informations