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Scientific article
English

The Reaction of 4-Hydroperoxy-2,4,6-trimethylcyclohexa-2,5-dienone with Acetaldehyde. Formation of the Bis(peroxyacetal)

Published inHelvetica chimica acta, vol. 67, no. 7, p. 1952-1956
Publication date1984-11-07
Abstract

The reaction of 4-hydroperoxy-2,4,6-trimethylcyclohexa-2,5-dienone with acetaldehyde using trimethylsilyl trifluoromethanesulfonate as catalyst gives 1,1′-bis[(1,3,5-trimethyl-4-oxo-2,5-cyclohexadienyl) peroxy]diethyl ether (7) in 70% yield. The structure of this unusual acetal was determined by X-ray analysis.

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Citation (ISO format)
JEFFORD, Charles, BERNARDINELLI, Gérald Hugues, MCGORAN, Ernest C. The Reaction of 4-Hydroperoxy-2,4,6-trimethylcyclohexa-2,5-dienone with Acetaldehyde. Formation of the Bis(peroxyacetal). In: Helvetica chimica acta, 1984, vol. 67, n° 7, p. 1952–1956. doi: 10.1002/hlca.19840670733
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ISSN of the journal0018-019X
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