Nuclear quadrupole resonance studies of chelated antimony complexes. Part 5. Eight-membered rings containing phosphorus or sulphur

Gerard, Claudine; Lucken, Edwin-Anthony

doi:10.1016/S0020-1693(00)88099-8

Scientific article

English

Nuclear quadrupole resonance studies of chelated antimony complexes. Part 5. Eight-membered rings containing phosphorus or sulphur

ContributorsGerard, Claudine; Lucken, Edwin-Anthony

Published inInorganica Chimica Acta, vol. 134, no. 2, p. 293-295

Publication date1987-11

Abstract

The ³⁵Cl Nuclear Quadrupole Resonance spectra of two cyclic phosphorus-containing compounds, ((CH₃)₂PO₂SbCl₄)₂ and (Cl₂PO₂SbCl₄)₂, and five sulphur-containing compounds, (RSO₃SbCl₄)₂, which have been supposed to have similar structures, are reported. The NQR spectra support the hypothesis that the sulphur compounds have similar structures to the phosphorus compounds while showing that for (FSO₃SbCl₄)₂ the symmetry of the eight- membered ring is different from that of the other six compounds.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie physique

Citation (ISO format)

GERARD, Claudine, LUCKEN, Edwin-Anthony. Nuclear quadrupole resonance studies of chelated antimony complexes. Part 5. Eight-membered rings containing phosphorus or sulphur. In: Inorganica Chimica Acta, 1987, vol. 134, n° 2, p. 293–295. doi: 10.1016/S0020-1693(00)88099-8

Article (Published version)

Identifiers

PID : unige:167614
DOI : 10.1016/S0020-1693(00)88099-8

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/S0020169300880998

Journal ISSN0020-1693

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Nuclear quadrupole resonance studies of chelated antimony complexes. Part 5. Eight-membered rings containing phosphorus or sulphur

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