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Fused Indolines by Palladium-Catalyzed Asymmetric C-C Coupling Involving an Unactivated Methylene Group

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Published in Angewandte Chemie: International Edition. 2011, vol. 50, no. 32, p. 7438-7441
Abstract Selectivity at high temperatures: Bulky, thermally stable, chiral palladium complexes generated from N-heterocyclic carbenes (NHCs; see picture) were successfully applied to the synthesis of highly enantioenriched trans-fused indolines. Remarkably, this reaction occurs at elevated temperatures with excellent asymmetric recognition of an enantiotopic C-H bond in an unactivated methylene unit.
Keywords Asymmetric catalysisC-H activationIndolinesN-heterocyclic carbenesPalladium
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Other version: http://doi.wiley.com/10.1002/anie.201102639
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NAKANISHI, Masafumi et al. Fused Indolines by Palladium-Catalyzed Asymmetric C-C Coupling Involving an Unactivated Methylene Group. In: Angewandte Chemie: International Edition, 2011, vol. 50, n° 32, p. 7438-7441. https://archive-ouverte.unige.ch/unige:16744

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Deposited on : 2011-08-05

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