An unusual stereospecific epoxidation with “per-amberlyst 15<sup>®</sup>”

Jefford, Charles; Bernardinelli, Gérald Hugues; Rossier, Jean-Claude; Kohmoto, Shigeo; Boukouvalas, John

doi:10.1016/S0040-4039(00)89161-3

Scientific article

English

An unusual stereospecific epoxidation with “per-amberlyst 15^®”

ContributorsJefford, Charles; Bernardinelli, Gérald Hugues; Rossier, Jean-Claude; Kohmoto, Shigeo; Boukouvalas, John

Published inTetrahedron letters, vol. 26, no. 5, p. 615-618

Publication date1985

Abstract

4-Methyl-4-naphthoquinol and its 5-methyl derivative on treatment with per-Amberlyst 15 are converted to the corresponding cis-2,3-epoxides in high yields. The latter structure was determined by X-ray crystallography.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

JEFFORD, Charles et al. An unusual stereospecific epoxidation with “per-amberlyst 15^®”. In: Tetrahedron letters, 1985, vol. 26, n° 5, p. 615–618. doi: 10.1016/S0040-4039(00)89161-3

Article (Published version)

Identifiers

PID : unige:167415
DOI : 10.1016/S0040-4039(00)89161-3

Additional URL for this publicationhttps://linkinghub.elsevier.com/retrieve/pii/S0040403900891613

Journal ISSN0040-4039

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An unusual stereospecific epoxidation with “per-amberlyst 15®”

4-Methyl-4-naphthoquinol and its 5-methyl derivative on treatment with per-Amberlyst 15 are converted to the corresponding cis-2,3-epoxides in high yields. The latter structure was determined by X-ray crystallography.

Technical informations

An unusual stereospecific epoxidation with “per-amberlyst 15^®”