Electrophilic Catalysis in lodosylbenzene Oxidation of Aromatic Derivatives

Muller, Paul; Gilabert, David Manuel

Scientific article

English

Electrophilic Catalysis in lodosylbenzene Oxidation of Aromatic Derivatives

ContributorsMuller, Paul; Gilabert, David Manuel

Published inChimia, vol. 40, no. 4, p. 127-128

Publication date1986-04

Abstract

The oxidation of activated aromatic compounds (phenols and hydroquinones) is cacalyzed by BF₃ or RuCl₂(PPh₃)₃. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species, in analogy to the effect of BF₃.

Affiliation entities

Faculté des sciences / Section de chimie et biochimie / Département de chimie organique

Citation (ISO format)

MULLER, Paul, GILABERT, David Manuel. Electrophilic Catalysis in lodosylbenzene Oxidation of Aromatic Derivatives. In: Chimia, 1986, vol. 40, n° 4, p. 127–128.

Article (Published version)

CC BY

Identifiers

PID : unige:167141

Journal ISSN0009-4293

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Electrophilic Catalysis in lodosylbenzene Oxidation of Aromatic Derivatives

The oxidation of activated aromatic compounds (phenols and hydroquinones) is cacalyzed by BF3 or RuCl2(PPh3)3. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species, in analogy to the effect of BF3.

Technical informations

The oxidation of activated aromatic compounds (phenols and hydroquinones) is cacalyzed by BF₃ or RuCl₂(PPh₃)₃. The catalytic effect of the ruthenium is ascribed to electrophilic catalysis, due to complexation between iodosylbenzene and the Ru species, in analogy to the effect of BF₃.