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Scientific article
English

Asymmetric additions of 1-alkenylcopper reagents to chiral enoates: enantioselective synthesis of california red scale pheromone

Published inTetrahedron letters, vol. 27, no. 10, p. 1139-1140
Publication date1986
Abstract

nBu3P-stabilized 1-alkenylcopper reagents undergo efficient 1,4-additions to enoates 1 and 5. Thus, acids 3, 7 or alcohols 4, 8 were obtained in high e.e. with recovery of the auxiliary. 4d was converted to pure (-)-pheromone 13, and 8b gave bromide 14b.

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Citation (ISO format)
VON OPPOLZER, Wolfgang, STEVENSON, Thomas Martin. Asymmetric additions of 1-alkenylcopper reagents to chiral enoates: enantioselective synthesis of california red scale pheromone. In: Tetrahedron letters, 1986, vol. 27, n° 10, p. 1139–1140. doi: 10.1016/S0040-4039(00)84198-2
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ISSN of the journal0040-4039
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